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KMID : 1059520100540010125
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Journal of the Korean Chemical Society
2010 Volume.54 No. 1 p.125 ~ p.130
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Kinetic and Thermodynamic Studies of Brilliant Green Adsorption onto Carbon/Iron Oxide Nanocomposite
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Rais Ahmad
Rajeev Kumar
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Abstract
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In the present work, we have investigated the adsorption efficiency of carbon/iron oxide nanocomposite towards removal of hazardous brilliant green (BG) from aqueous solutions. Carbon/iron oxide nanocomposite was prepared by chemical precipitation and thermal treatment of carbon with ferric nitrate at 750oC. The resulting material was thoroughly characterized by TEM, XRD and TGA. The adsorption studies of BG onto nanocomposite were performed using kinetic and thermodynamic parameters. The adsorption kinetics shows that pseudo-second-order rate equation was fitted better than pseudo-first-order rate equation. The experimental data were analyzed by the Langmuir and Freundlich adsorption isotherms. Equilibrium data was fitted well to the Langmuir model with maximum monolayer adsorption capacity of 64.1 mg/g. The thermodynamic parameters were also deduced for the adsorption of BG onto nanocomposite and the adsorption was found to be spontaneous and endothermic.
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KEYWORD
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Nanocomposite, Adsorption, Kinetic, Thermodynamic, Desorption
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